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Bis(3-hydroxymethylanilinium) hexachloridostannate(IV)

Sofiane Bouacida, Habiba Kechout, Ratiba Belhouas and 2 more

Acta Crystallographica Section E · 2011

doi:10.1107/s1600536811007252 (opens in a new tab)

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Abstract

In the title compound, (C7H10NO)2[SnCl6], the SnIV atom, located on an inversion center, exists in an octahedral coordination environment. The crystal structure exhibits alternating organic and inorganic layers parallel to (overline{1}01). The cations and anions are linked via intermolecular N—H...O, N—H...Cl and O—H...Cl hydrogen bonds. Additional stabilization is provided by π–π stacking interactions between the benzene rings of the cations [centroid–centroid distances = 3.6962 (15) and 3.9340 (15) Å].

Abstract licence: CC BY

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