Bis(N,N,N-trimethylethanaminium) bis(1,4-tetraselenido-κ2Se1,Se4)cadmate
Jaemyeong Kim, Kang-Woo Kim
Acta Crystallographica Section E · 2011
doi:10.1107/s1600536811007227 (opens in a new tab)
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Abstract
The title compound, (EtMe3N)2[Cd(Se4)2], which has been prepared by reaction of CdI2, K2Se4 and EtMe3NI in dimethylformamide, is the first example of a [Cd(Se4)2]2− anion stabilized by alkylammonium counter-ions. The Cd atom in the complex [Cd(Se4)2]2− anion is tetrahedrally coordinated by two chelating tetraselenide ligands, and both CdSe4 rings exhibit an envelope conformation.
Abstract licence: CC BY
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