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Bis(μ-chloroacetato-κ2O:O′)bis(chloroacetato-κO)di-μ3-oxido-tetrakis[dibenzyltin(IV)]

Jing Li, Handong Yin, Daqi Wang

Acta Crystallographica Section E · 2011

doi:10.1107/s1600536810054000 (opens in a new tab)

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Abstract

The title tetranuclear complex molecule, [Sn4(C7H7)8(C2H2ClO2)4O2], has crystallographically imposed inversion symmetry. Each Sn atom has a distorted trigonal–bipyramidal geometry, with the equatorial plane formed by an oxido O atom and two C atoms of two benzyl anions. The configuration of the complex is stabilized by a pair of C—H...O hydrogen bonds. In the crystal, complex molecules are linked into zigzag chains along [110] by C—H...O hydrogen bonds.

Abstract licence: CC BY

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