[μ-1,2-Bis(diphenylphosphanyl)benzene-κ2P:P′]bis[chloridogold(I)]

In the crystal structure of the non-solvate form of the title compound, [Au2Cl2(C30H24P2)], two almost linear P—AuI—Cl units [175.87 (3) and 171.48 (3)°] are in a skewed arrangement with a Cl—Au...Au—Cl torsion angle of −65.29 (3)° so as to form an intramolecular Au...Au interaction [3.0563 (2) Å]. The complex molecules are connected each other through intermolecular C—H...π interactions, giving a sheet structure parallel to the bc plane.

Abstract licence: CC BY

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