(4,4′-Dimethyl-2,2′-bipyridine-κ2N,N′)(dimethyl sulfoxide-κO)diiodidozinc(II)
Mohammad Yousefi
Acta Crystallographica Section E · 2010
doi:10.1107/s1600536810046763 (opens in a new tab)
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Abstract
In the title compound, [ZnI2(C12H12N2)(C2H6OS)], the ZnII ion is coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide molecule and two I atoms in a distorted trigonal-bipyramidal geometry. Intramolecular C—H...O hydrogen bonds and intermolecular π–π stacking interactions between the pyridine rings [centroid–centroid distances = 3.637 (4) and 3.818 (4) Å] are present in the crystal structure.
Abstract licence: CC BY
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