μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate

In the binuclear title compound, [Mo2(C12H15N4O2)2Cl2O3]·H2O, the complex molecules have approximate C2 symmetry. Both MoV atoms have a distorted octahedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the MoV atom via an N2O donor set. The water molecule bridges two complex molecules, forming O—H...O and O—H...Cl hydrogen bonds to the acetate group and to the chloride ligands.

Abstract licence: CC BY

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