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Bis[μ-4-methyl-2-(2-pyridylmethylsulfanyl)pyrimidine-κN1]bis[(trifluoromethanesulfonato-κO)silver(I)]

Huan-Huan Wang, Chao-Yan Zhang, Yue Cui and 2 more

Acta Crystallographica Section E · 2010

doi:10.1107/s1600536810043631 (opens in a new tab)

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Abstract

In the centrosymmetric dinuclear title complex, [Ag2(CF3SO3)2(C11H11N3S)2], the AgI atom is coordinated by two N atoms from two 4-methyl-2-(2-pyridylmethylsulfanyl)pyrimidine ligands and one O atom from a trifluoromethanesulfonate anion in a distorted T-type coordination geometry. The ligand adopts a bidentate bridging coordination mode through one pyridyl N atom and one pyrimidine N atom. In the crystal structure, π–π interactions are present between adjacent pyrimidine rings, with a centroid-to-centroid distance of 3.875 (7) Å.

Abstract licence: CC BY

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