trans-Bromido(pyrimidinyl-κC2)bis(triphenylphosphane-κP)palladium(II)
Gene-Hsiang Lee, Hsiao-Fen Wang, Kuang-Hway Yih
Acta Crystallographica Section E · 2010
doi:10.1107/s1600536810038511 (opens in a new tab)
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Abstract
In the title complex, [PdBr(C4H3N2)(C18H15P)2], the geometry around the PdII atom is distorted square-planar with the PdII atom displaced by 0.0150 (5) Å from the least-squares BrP2C plane. Two PPh3 ligands are in trans positions [P—Pd—P = 176.743 (17)°], while the pyrimidinyl ligand and Br atom are trans to one another [C—Pd—Br = 176.56 (5)°]. Structural parameters from NMR, IR and mass spectra are in agreement with the crystal structure of the title compound.
Abstract licence: CC BY
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