Bromidotricarbonyl[4-iodo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]rhenium(I)
Ali Mahmoudi, Saeed Dehghanpour
Acta Crystallographica Section E · 2010
doi:10.1107/s1600536810037104 (opens in a new tab)
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Abstract
In the title compound, [ReBr(C12H9IN2)(CO)3], the coordination geometry of the ReI ion is a distorted fac-ReC3BrN2 octahedron, arising from the N,N′-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the 4-iodo-N-(pyridin-2-ylmethylidene)aniline ligand is 46.2 (3)°. The bromide ion and its corresponding trans CO molecule are disordered over two sets of sites in a 0.966 (3):0.034 (3) ratio.
Abstract licence: CC BY
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