A dimeric zinc(II) complex: bis[μ-1,2-bis(1,2,4-triazol-4-yl)ethane-κ2N1:N1′]bis[dinitritozinc(II)]

The coordination geometry of the ZnII atom in the title complex, [Zn2(NO2)4(C6H8N6)2], is distorted octahedral, in which the ZnII atom is coordinated by two N atoms from the triazole rings of two symmetry-related 1,2-bis(1,2,4-triazol-4-yl)ethane ligands and four O atoms from two nitrite ligands. Two ZnII atoms are bridged by two organic ligands, forming a centrosymmetric dimer. Weak C—H...N and C—H...O hydrogen bonds play an important role in the intermolecular packing.

Abstract licence: CC BY

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