catena-Poly[(S)-2-methylpiperazine-1,4-diium [[trichloridobismuthate(III)]-di-μ-chlorido]]

In the crystal structure of the title compound, {(C5H14N2)[BiCl5]}n, the BiIII cation is coordinated by six Cl− anions in a distorted octahedral geometry. Two Cl− anions bridge neighboring BiIII cations, forming a zigzag polymeric chain along the a axis. The discrete methylpiperazinediium cation adopts a normal chair conformation and is linked to the polymeric chains by N—H...Cl hydrogen bonding.

Abstract licence: CC BY

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