3,10-C-meso-3,5,7,7,10,12,14,14-Octamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate)
Tapashi G. Roy, Saroj K. S. Hazari, Kanak K. Barua and 2 more
Acta Crystallographica Section E · 2010
doi:10.1107/s1600536810030217 (opens in a new tab)
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Abstract
The structure determination of the title salt, C18H42N42+·2ClO4−, reveals that protonation has occurred at diagonally opposite amine N atoms. Intramolecular N—H...N hydrogen bonds stabilize the conformation of the dication. In the crystal, the dications are bridged by perchlorate ions via N—H...O hydrogen bonds into supramolecular chains propagating along the c axis and weak C—H...O interactions cross-link the chains.
Abstract licence: CC BY
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