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N-(3-Nitrophenyl)maleamic acid

B. Thimme Gowda, Miroslav Tokarčík, K. Shakuntala and 2 more

Acta Crystallographica Section E · 2010

doi:10.1107/s1600536810022245 (opens in a new tab)

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Abstract

In the title compound, C10H8N2O5, the molecule is slightly distorted from planarity. The molecular structure is stabilized by two intramolecular hydrogen bonds. The first is a short O—H...O hydrogen bond (H...O distance = 1.57 Å) within the maleamic acid unit and the second is a C—H...O hydrogen bond (H...O distance = 2.24 Å) which connects the amide group with the benzene ring. The nitro group is twisted by 6.2 (2)° out of the plane of the benzene ring. The crystal structure manifests a variety of hydrogen bonding. The packing is dominated by a strong intermolecular N—H...O interaction which links the molecules into chains running along the b axis. The chains within a plane are further assembled by three additional types of intermolecular C—H...O hydrogen bonds to form a sheet parallel to the (overline{1}01) plane.

Abstract licence: CC BY

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