Dicylopentadienyl[4-(4-vinylbenzyloxy)pyridine-2,6-dicarboxylato]titanium(IV) monohydrate
Fanghua Zhu, Yuancheng Qin, Jiehong Lei and 2 more
Acta Crystallographica Section E · 2010
doi:10.1107/s1600536810021148 (opens in a new tab)
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Abstract
The title compound, [Ti(C5H5)2(C16H11NO5)]·H2O, exhibits a titanocene unit coordinated to a styrene-substituted pyridine-2,6-dicarboxylate ligand synthesized for use as a monomer for polymerization or copolymerization yielding metallocene-containing polymers. The compound crystallized as a monohydrate and the solvent water molecule forms strong O—H...O hydrogen bonds with the carboxylate O atoms of the Ti complex, which play an important role in the connection of adjacent molecules. In addition, weak intermolecular C—H...O hydrogen bonds also contribute to the crystal packing arrangement.
Abstract licence: CC BY
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