{1,3-Bis[(diphenylphosphanyl-κP)oxy]prop-2-yl-κC2}iodido(trimethylphosphane)cobalt(II)
Guoqiang Xu, Xiaoyan Li
Acta Crystallographica Section E · 2010
doi:10.1107/s1600536810013747 (opens in a new tab)
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Abstract
The title compound, [Co(C27H25O2P2)I(C3H9P)], was synthesized by the addition of 1-iodobutane to a solution of the parent cobalt complex {1,3-bis[(diphenylphosphanyl)oxy]prop-2-yl}bis(trimethylphosphane)cobalt(II). Two five-membered cobaltocycles with considerable ring bending (sum of internal angles = 516.4 and 517.7°) are formed through two P atoms of the PPh2 groups and a metallated Csp3 atom. The CoII atom is centered in a trigonal-bipyramidal configuration.
Abstract licence: CC BY
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