Dilead(II) chromium(III) heptafluoride
Armel Le Bail
Acta Crystallographica Section E · 2010
doi:10.1107/s1600536810011608 (opens in a new tab)
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Abstract
Single crystals of the title compound, Pb2CrF7, were obtained by solid-state reaction. The monoclinic structure is isotypic with Pb2RhF7 and is built up of CrF63− octahedra isolated from each other, inserted in a fluorite-related matrix of PbF6 distorted octahedra, and PbF8 square antiprisms sharing edges and corners. The seventh F atom is `independent', connected only to three Pb atoms within FPb3 triangles, sharing an edge and building an almost planar Pb4F2 unit, so that the formula can alternatively be written as Pb2F(CrF6).
Abstract licence: CC BY
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