2-(1,3-Thiazol-4-yl)benzimidazolium nitrate monohydrate
Marcos Flores-Alamo, Sandra González-Martínez, Silvia E. Castillo-Blum
Acta Crystallographica Section E · 2010
doi:10.1107/s1600536810008433 (opens in a new tab)
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Abstract
In the title compound, C10H8N3S+·NO3−·H2O, one of the N atoms of the benzimidazole unit is protonated, unlike than that in the thiazole group. This protonation leads to equalization of the bond angles at the two N atoms of the benzimidazole group. The benzimidazole and thiazole systems are almost coplanar, forming a dihedral angle of 0.5 (2)°. In the crystal, the nitrate anion and water molecule bridge the thiabendazolium cations through N—H...O and O—H...O hydrogen bonds, leading to a supramolecular network based on an infinite one-dimensional chain using [001] as base vector.
Abstract licence: CC BY
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