Poly[[(μ3-isonicotinato-κ3O:O:N)(triphenylphosphine-κP)silver(I)] ethanol solvate]
Seik Weng Ng, Mostafa M. Amini, Omid Sadeghi
Acta Crystallographica Section E · 2010
doi:10.1107/s1600536810004733 (opens in a new tab)
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Abstract
In the crystal structure of {[Ag(C6H4NO2)(C18H15P)]·C2H6O}n, the 4-pyridylcarboxylate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitrogen atom of the aromatic ring, giving a distorted tetrahedral coordination at the metal atom. The μ3-bridging mode leads to a layer motif; the disordered ethanol molecules are linked to the free carboxyl oxygen atom by O—H...O hydrogen bonds.
Abstract licence: CC BY
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