Poly[[tris(μ3-2-oxidopyridinium-3-carboxylato)manganese(II)sodium(I)] monohydrate]
Bing-Yu Zhang, Jing-Jing Nie, Duan-Jun Xu
Acta Crystallographica Section E · 2010
doi:10.1107/s1600536810002953 (opens in a new tab)
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Abstract
In the crystal structure of the title compound, {[MnNa(C6H4NO3)3]·H2O}n, the MnII cation is located on a threefold rotation axis and is chelated by three 2-oxidopyridinium-3-carboxylate (opc) anions in an octahedal coordination. The NaI cation is located on a threefold rotation axis and is surrounded by six O atoms from three opc anions. The opc anions link the Mn and Na cations, forming a three-dimensional polymeric structure. The uncoordinated water molecule, located on a threefold rotation axis, is equally disordered over two sites. The three-dimensional network is consolidated by N—H...O hydrogen bonds.
Abstract licence: CC BY
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