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Bis{2-ethoxy-6-[2-(methylammonio)ethyliminomethyl]phenolato}thiocyanatozinc(II) nitrate

Chen-Yi Wang, Zhi-Ping Han, Xiang Wu and 2 more

Acta Crystallographica Section E · 2010

doi:10.1107/s1600536810000036 (opens in a new tab)

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Abstract

In the title compound, [Zn(NCS)(C12H18N2O2)2]NO3, the ZnII ion is chelated by the phenolate O and imine N atoms from two zwitterionic Schiff base ligands and is also coordinated by the N atom of a thiocyanate ligand, giving a distorted trigonal-bipyramidal geometry. Intramolecular N—H...O hydrogen bonds are observed in the complex cation. The nitrate anions are linked to the complex cations through N—H...O hydrogen bonds.

Abstract licence: CC BY

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