6-(1-Methylethyl)-12-phenyl-5,6,7,12-tetrahydrodibenz[c,f][1,5]azasilocine
Kei Goto, Akihiro Fukushima, Takayuki Kawashima
Acta Crystallographica Section E · 2010
doi:10.1107/s1600536809050909 (opens in a new tab)
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Abstract
The title compound, C23H25NSi, has an eight-membered silicon-containing heterocyclic ring with an intramolecular N...Si close contact, the transannular distance of which is 2.6294 (18) Å. The resulting geometry about the Si atom is distorted trigonal-bypyramidal, with the N and H atoms occupying apical sites. The dihedral angle between the aromatic rings fused to the eight-membered ring is 63.27 (7)°.
Abstract licence: CC BY
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