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Dichloridobis(1,10-phenanthroline-5,6-dione-κ2N,N′)mercury(II)

Edward R. T. Tiekink, James L. Wardell, R. Alan Howie and 2 more

Acta Crystallographica Section E · 2009

doi:10.1107/s1600536809049289 (opens in a new tab)

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Abstract

In the title compound, [HgCl2(C12H6N2O2)2], the HgII atom is located on a twofold rotation axis and exists within a distorted octahedral geometry defined by a cis-Cl2N4 donor set. Molecules are connected into layers in the ac plane via extensive C—H...Cl contacts as each Cl atom forms two such interactions. Contacts between the layers are of the type C=O...π [O...centroid distance = 3.110 (8) Å].

Abstract licence: CC BY

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