μ-2-Aminoterephthalato-κ2O1:O4-bis[triphenyltin(IV)]
Wenkuan Li, Handong Yin, Lei Dong and 2 more
Acta Crystallographica Section E · 2009
doi:10.1107/s1600536809043554 (opens in a new tab)
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Abstract
The title compound, [Sn(2)(C(6)H(5))(6)(C(8)H(5)NO(4))], contains two triphenyl-tin groups bridged by a 2-amino-terephthalate ligand. The two Sn(IV) centers have similar distorted tetra-hedral coordination geometries. Each Sn(IV) atom is bonded to three phenyl C atoms and one O atom from a carboxyl-ate group. The other O atom of the carboxyl-ate group has a weak inter-action with the Sn atom. The amino group is disordered over two sites, with site-occupancy factors of 0.779 (11) and 0.221 (11). Intra-molecular N-H⋯O hydrogen bonds are observed.
Abstract licence: CC BY
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