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Hydronium 4-oxo-1,4-dihydropyridine-3-sulfonate dihydrate

Zhi-Biao Zhu, Shan Gao, Seik Weng Ng

Acta Crystallographica Section E · 2009

doi:10.1107/s1600536809040641 (opens in a new tab)

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Abstract

2-Hydroxypyridine when treated with concentrated sulfuric acid is sulfonated at the 3-position to yield the title hydrated salt, H3O+·C5H4NO3S−·2H2O. In the crystal structure, the cations, anions and uncoordinated water molecules are linked by extensive O—H...O and N—H...O hydrogen bonds into a three-dimensional network. The crystal studied is a non-merohedral twin with a twin component of 36%.

Abstract licence: CC BY

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