Bis(acetylacetonato-κ2O,O′)aqua(diacetylmethanido-κC)iridium(III)
Qiao-Wen Chang, Ming-Jin Xie, Wei-Ping Liu and 2 more
Acta Crystallographica Section E · 2009
doi:10.1107/s160053680903760x (opens in a new tab)
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Abstract
In the crystal structure of the title compound, [Ir(C5H7O2)3(H2O)], the IrIII atom is six-coordinated and situated in a slightly distorted octahedral environment. The complex contains both Ir—O and Ir—C bonds and was isolated from a reaction mixture of IrCl3(H2O)x, pentane-2,5-dione and NaHCO3. O—H...O hydrogen bonding between the water molecules and the carbonyl O atoms of adjacent molecules leads to a layered motif extending parallel to (010).
Abstract licence: CC BY
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