Methyl (Sp)-2-(diphenylphosphino)ferrocene-1-carboxylate
Petr Štěpnička, Jiří Tauchman, Ivana Císařová
Acta Crystallographica Section E · 2009
doi:10.1107/s1600536809036654 (opens in a new tab)
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Abstract
The title compound, [Fe(C5H5)(C19H16O2P)], obtained serendipitously during recrystallization of 1-hydroxybenzotriazolyl (Sp)-2-(diphenylphosphino)ferrocene-1-carboxylate from methanol, crystallizes in the chiral space group P212121. Its crystal structure not only confirms the anticipated absolute configuration but also establishes a rather regular geometry for the ferrocene unit, devoid of any significant deformation due to the attached substituents. In the crystal, symmetry-related molecules are linked via weak C—H...O interactions.
Abstract licence: CC BY
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