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Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]

Karyn M. Blake, Robert L. LaDuca

Acta Crystallographica Section E · 2009

doi:10.1107/s1600536809027767 (opens in a new tab)

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Abstract

In the title compound, {[CdCl2(C16H20N4)2]·4H2O}n, octahedrally coordinated CdII ions, situated on crystallographic inversion centres, bearing trans-disposed chloride ligands, are linked into (4,4)-grid coordination polymer layers by tethering 1,4-bis(3-pyridylmethyl)piperazine ligands. The layers are aligned parallel to the (overline{1}01) crystal planes and aggregate by means of O—H...N, O—H...O and O—H...Cl hydrogen-bonding mechanisms imparted by cyclic water molecule tetramers.

Abstract licence: CC BY

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