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2-(1,2,3,4-Tetrahydrophenanthren-1-ylidene)malononitrile

George B. Ettenger, Brian Wesley Williams, Daniel Brillhart and 1 more

Acta Crystallographica Section E · 2009

doi:10.1107/s1600536809023988 (opens in a new tab)

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Abstract

In the title complex, C17H12N2, the non-aromatic six-membered ring adopts an envelope conformation. The dihedral angle between the eight-membered plane containing the malononitrile group and the aromatic system is 25.88 (4)°. The distance from the central C atom of the malononitrile group to the centroid of the n-glide-related distal aromatic ring is 3.66 Å, suggesting π–π interactions.

Abstract licence: CC BY

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