catena-Poly[[triphenyltin(IV)]-μ-2-[(3,5-di-tert-butyl-4-hydroxybenzyl)sulfanyl]acetato-κ2O:O′]
See Mun Lee, Kong Mun Lo, Hapipah Mohd Ali and 1 more
Acta Crystallographica Section E · 2009
doi:10.1107/s1600536809023150 (opens in a new tab)
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Abstract
The title compound, [Sn(C6H5)3(C17H25O3S)]n, comprises two symmetry-independent five-coordinated triphenyltin molecules which are linked by carboxylate bridges into a polymeric chain. The SnIV atom is in a distorted trans-C3SnO2 trigonal-bipyramidal geometry. The presence of two bulky tert-butyl groups on the benzene ring prevents any hydrogen-bonding interactions involving the hydroxyl substituents.
Abstract licence: CC BY
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