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RbCa2Nb3O10 from X-ray powder data

Zhen-Hua Liang, Kai-Bin Tang, Qian-Wang Chen and 1 more

Acta Crystallographica Section E · 2009

doi:10.1107/s1600536809018157 (opens in a new tab)

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Abstract

Rubidium dicalcium triniobate(V), RbCa 2 Nb 3 O 10 , has been synthesized by solid-state reaction and its crystal structure refined from X-ray powder diffraction data using Rietveld analysis. The compound is a three-layer perovskite Dion–Jacobson phase with the perovskite-like slabs derived by termination of the three-dimensional CaNbO 3 perovskite structure along the ab plane. The rubidium ions (4/ mmm symmetry) are located in the interstitial space.

Abstract licence: CC BY

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