The ansa-bridged cyclopentadienyl titanium complex [{η5-C5Me4CH2-C(NMe2)=N}TiCl2]
Donglong Guo, Hong-Bo Tong, Meisu Zhou
Acta Crystallographica Section E · 2009
doi:10.1107/s1600536809015839 (opens in a new tab)
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Abstract
The title complex, dichlorido[ N , N -dimethyl-2-(η 5 -tetramethylcyclopentadienyl)acetamidinido-κ N ′]titanium(IV), [Ti(C 13 H 20 N 2 )Cl 2 ], exhibits an unusual ansa -bridged conformation. The cyclopentadienyl ring and the mean plane of the Ti—N=C—C—C fragment form a dihedral angle of 88.08 (11)°.
Abstract licence: CC BY
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