catena-Poly[[[pyridinecopper(II)]-(μ-2-oxidonaphthalene-1-carbaldehyde picolinoylhydrazonato)-[pyridinecopper(II)]-μ-sulfato] diethyl ether hemisolvate]
Daqi Wang, Dacheng Li, Quanchang Wang
Acta Crystallographica Section E · 2009
doi:10.1107/s1600536809012653 (opens in a new tab)
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Abstract
The title compound, {[Cu2(C17H11N3O)(SO4)(C5H5N)2]·0.5C4H10O}n, was synthesized by the reaction of 2-hydroxy-1-naphthylaldehyde-2-pyridinecarboxylhydrazone with copper sulfonate. A one-dimensional polymer was obtained via self-assembly. Each Cu ion is located in a distorted square-pyramidal coordination environment, with one Cu ion coordinated by two N and three O atoms, while the other links to two O and three N atoms. In the crystal, weak intermolecular C—H...O interactions connect the chains into a two-dimensional network.
Abstract licence: CC BY
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