Bis[tris(4-fluorophenyl)phosphine-κP](tropolonato-κ2O,O′)copper(I)

The title compound, [Cu(C7H5O2)(C18H12F3P)2], a copper(I) tris(4-fluorophenyl)phosphine tropolonate derivative, is the first tropolonate complex with fluorinated arylphosphine ligands. The CuI atom has a distorted tetrahedral coordination; the most important geometrical parameters of the molecule are: Cu—P = 2.2377 (10) and 2.2335 (15) Å, Cu—O = 2.084 (2) and 2.082 (2) Å, O—Cu—O = 77.72 (10)°, P—Cu—P = 128.82 (4)° and O—C—C—O = −2.1 (5)°.

Abstract licence: CC BY

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