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Poly[[tris[μ-2,2′-(butane-1,4-diyldithio)bis(1,3,4-thiadiazole)-κ2N4:N4′]copper(II)] bis(perchlorate)]

Acta Crystallographica Section E · 2009

doi:10.1107/s1600536809005625 (opens in a new tab)

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Abstract

In the title compound, {[Cu(C8H10N4S4)3](ClO4)2}n, the CuII atom is located on a threefold inversion axis coordinated by six N atoms of symmetry-equivalent 2,2′-(butane-1,4-diyldithio)bis(1,3,4-thiadiazole) ligands in a slightly distorted octahedral geometry. Adjacent CuII atoms are linked by the bridging bidentate thiadiazole ligands, which are situated about inversion centers. This leads to the formation of a three-dimensional network structure.

Abstract licence: CC BY

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