catena-Poly[[bis(5-chloro-2-nitrobenzoato)copper(II)]-bis(μ-5-chloro-2-nitrobenzoato)]
Hoong-Kun Fun, Ibrahim Abdul Razak, Siang Guan Teoh and 1 more
Acta Crystallographica Section E · 2009
doi:10.1107/s1600536809001895 (opens in a new tab)
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Abstract
In the title compound, [Cu2(C7H3ClNO4)4]n, the coordination geometry around each CuII ion is distorted square-pyramidal. The CuO5 coordination is formed by five O atoms from the carboxylate groups of five 5-chloro-2-nitrobenzoate ligands. This coordination leads to the formation of centrosymmetric binuclear units which are edge-shared, forming a linear chain along the a axis, with the CuII ions alternately separated by 2.5891 (4) and 3.1763 (4) Å. The chains are interconnected into a three-dimensional network by C—H...O interactions.
Abstract licence: CC BY
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