Aqua(iminodiacetato-κ3O,N,O′)(1,10-phenanthroline-κ2N,N′)cobalt(II) monohydrate
Hwa Loong Ng, Chew Hee Ng, Seik Weng Ng
Acta Crystallographica Section E · 2009
doi:10.1107/s1600536808041226 (opens in a new tab)
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Abstract
The iminodiacetate dianion in the title compound, [Co(C4H5NO4)(C12H8N2)(H2O)]·H2O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octahedron around the metal atom. The metal atom is also chelated by the N-heterocycle. The dianion, and coordinated and uncoordinated water molecules interact through hydrogen bonds, generating a layer motif. The crystal studied was a racemic twin with a 0.62 (2):0.38 (2) domain ratio.
Abstract licence: CC BY
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