Poly[4,4′-iminodipyridinium [tetra-μ3-oxido-tetraoxido-di-μ4-phosphato-κ4O:O′:O′′:O′′′-tetravanadium(V)]]
Robert L. LaDuca, Gregory A. Farnum
Acta Crystallographica Section E · 2008
doi:10.1107/s1600536808038348 (opens in a new tab)
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Abstract
In the title salt, {(C10H11N3)[V4O8(PO4)2]}n, cubane-like [V4O8]4+ clusters are connected by phosphate anions into anionic [V4P2O16]n2n− layers. These aggregate into the three-dimensional structure via N—H...O hydrogen-bonding mechanisms imparted by 4,4′-iminodipyridinium dications situated between the layers.
Abstract licence: CC BY
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