catena-Poly[[di-μ-chlorido-bis{[6-methoxy-2-(4-methylphenyliminiomethyl)phenolato-κ2O,O′]cadmium(II)}]-di-μ2-thiocyanato-κ2N:S;κ2S:N]
Guo-Liang Zhao, Jian-Feng Liu, Hui-Duo Xian and 1 more
Acta Crystallographica Section E · 2008
doi:10.1107/s1600536808038099 (opens in a new tab)
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Abstract
The asymmetric unit of the title compound, [Cd2Cl2(NCS)2(C15H15NO2)2]n, contains the Schiff base 2-[(4-methylphenylimino)methyl]-6-methoxyphenol (HL) ligand, one thiocyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via two thiocyanate and two chloride bridges alternately, resulting in centrosymmetric zigzag chains running parallel to the a axis. The CdII coordination environment contains two Cl atoms, one thiocyanate (SCN) S atom, one isothiocyanate (NCS) N atom and two O atoms from the HL ligand. The Schiff base ligand is in the trans conformation.
Abstract licence: CC BY
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