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Bis(ethylenedithio)tetrathiafulvalenium–tetrachloridocobaltate(II) (3/2)

Lihua Dong, Xiaohui Zhu, Ping Li and 1 more

Acta Crystallographica Section E · 2008

doi:10.1107/s1600536808033692 (opens in a new tab)

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Abstract

The structure of the electrochemically crystallized title compound, (C10H8S8)3[CoCl4]2, consists of two types of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) radical cation stacks separated by sheets of tetrahedral [CoCl4]2− anions. One of the BEDT-TTF molecules is generated by inversion. There are short S...S contacts between the stacks in the a direction and short C—H...Cl contacts between the radical cations and the anions.

Abstract licence: CC BY

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