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catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ2N,N′)cadmium(II)]-di-μ-chlorido]

Hamid Reza Khavasi, Vahid Amani, Khadijeh Kalateh and 2 more

Acta Crystallographica Section E · 2008

doi:10.1107/s1600536808027657 (opens in a new tab)

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Abstract

The asymmetric unit of the title compound, [CdCl2(C12H12N2)]n, contains one half-molecule; a twofold rotation axis passes through the Cd atom. The CdII atom is six-coordinated in a distorted octahedral configuration by two N atoms from 2,2′-bipyridine-5,5′-dimethyl and four bridging Cl atoms. The bridging function of the chloro atoms leads to a one-dimensional chain structure. There is a π–π contact between the pyridine rings [centroid–centroid distance = 3.9807 (9) Å].

Abstract licence: CC BY

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