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Substitutional disorder in the substituted nixantphos ligand C39H32Br0.27Cl0.73NOP2

Holger B. Friedrich, Muhammad D. Bala, Thashree Marimuthu

Acta Crystallographica Section E · 2008

doi:10.1107/s1600536808007848 (opens in a new tab)

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Abstract

The structure of 10-(3-bromo/chloropropyl)-4,6-bis(diphenylphosphino)-10H-phenoxazine, C39H32Br0.27Cl0.73NOP2, shows chloro/bromo substitutional disorder in a 3:1 ratio. For application as a ligand in catalysis, the intramolecular P...P distance of 4.263 (2) Å is relevant. The phenoxazine ring system is essentially planar.

Abstract licence: CC BY

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