μ-Pyrazine-2,5-dicarboxylato-bis[chlorido(η6-p-cymene)ruthenium(II)] tert-butanol disolvate
Martin B. Smith, Mark R. J. Elsegood, Noelia M. Sanchez Ballester
Acta Crystallographica Section E · 2008
doi:10.1107/s1600536808000202 (opens in a new tab)
We email you when a new notice or a question about this paper appears.
Abstract
A new tert-butanol solvate of [{(iPrC6H4Me)RuCl}2{μ-2,5-pyz(COO)2}] (pyz = pyrazine) has been crystallized and structurally characterized. The solvate, [Ru2(C10H14)2(C6H2N2O4)Cl2]·2C4H10O, contains one half-molecule of the ruthenium(II) complex and one molecule of tert-butanol in the asymmetric unit. The complex molecule lies on an inversion centre with the two chlorides trans. In contrast, the previously reported structure was solvent-free. Similar metric parameters are found between the butanol solvate and the solvent-free form and an intermolecular O—H...O hydrogen bond exists between μ-pyrazine-2,5-dicarboxylato-bis[chlorido(η6-p-cymene)ruthenium(II)] and the tert-butanol molecule.
Abstract licence: CC BY
Reads
Read by people on this page
None yet.
Checked or read by AI through naulon
None yet.
A person counts once a day per paper. We keep no cookie and no address: a reader is a hash that changes every day. Any month under five reads shows no number.
Are you an author?
Is this your paper?
Claim it to add your note and be paid when agents cite it. Free.