A one-dimensional zigzag coordination polymer: catena-poly[[[triaquacadmium(II)]-[μ-2,2′-(5-methyl-1,3-phenylenedioxy)diacetato-κ4O,O′:O′′,O′′′]] monohydrate]
Hong-Tao Zhang, Xian-Wen Wei, Yun Wei and 1 more
Acta Crystallographica Section E · 2008
doi:10.1107/s1600536807068031 (opens in a new tab)
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Abstract
In the title one-dimensional coordination polymer, {[Cd(C11H10O6)(H2O)3]·H2O}n, the 2,2′-(5-methyl-1,3-phenylenedioxy)diacetate dianions connect CdII ions in a head-to-tail fashion to generate zigzag chains. The coordination geometry of the Cd atom is distorted pentagonal bipyramidal. There are O—H...O hydrogen bonds between the carboxyl O atoms, the aqua ligands and the uncoordinated water molecules.
Abstract licence: CC BY
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