Bis[2-(pyrimidin-2-ylamino)pyrimidinium] hexamolybdate
Chun-Wei Yeh, Chia-Her Lin, Jhy-Der Chen
Acta Crystallographica Section E · 2008
doi:10.1107/s1600536807062897 (opens in a new tab)
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Abstract
The title compound, (C8H8N5)2[Mo6O19], was prepared by reaction of Mo(CO)6 and dipyrimidylamine in refluxing toluene. The hexanuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intramolecular N—H...N hydrogen bond and the cations are linked through self-complementary pairs of N—H...N hydrogen bonds into dimers across centres of inversion. The cations and anions are interlinked through C—H...O contacts.
Abstract licence: CC BY
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