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Poly[[aqua(1-naphthylacetato)cadmium(II)]-μ3-pyridin-3-olato]

Chun-Yan Ma, Wen-Dong Song, Dan-Li Xi

Acta Crystallographica Section E · 2008

doi:10.1107/s1600536807062332 (opens in a new tab)

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Abstract

In the title complex, [Cd(C5H4NO)(C12H9O2)(H2O)]n, each CdII atom is coordinated by two carboxylate O atoms from one 1-naphthylacetate ligand, two hydroxyl O atoms from two pyridin-3-olate ligands, one N atom from another pyridin-3-olate ligand and one water molecule, and displays a distorted octahedral coordination geometry. The compound forms infinite chains of pyridin-3-olate ligands bridging 1-naphthylacetate–CdII units parallel to the b axis, with a Cd...Cd separation of 3.578 (2) Å. The chains are further self-assembled into a supramolecular network through intermolecular O—H...O hydrogen-bonding interactions.

Abstract licence: CC BY

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