Thermal stability improvement of polysiloxane-grafted insulating paper cellulose in micro-water environment

In order to improve the thermal stability of insulation paper cellulose in micro-water environment, the molecular simulation was used to compare and analyze the thermal stability of polysiloxane-grafted cellulose with 3% micro-water content in the present study. The static mechanics, glass transition temperature and number of hydrogen bonds are used to characterize the thermal stability of insulating paper cellulose in this paper. First, analysis of the mechanical properties of the model demonstrated that the value of the elastic moduli (E) and bulk moduli (K) of the grafted model were greater than those of the ungrafted model at each temperature. Second, the glass transition temperature of the grafted model was 60 K higher than that of the ungrafted model. Finally, the analysis of the radial distribution function (RDF) and hydrogen bonding showed that polysiloxane-grafted insulation paper cellulose can reduce the number of hydrogen bonds formed between the water molecules and the cellulose chains, which can reduce the damage caused to the cellulose chains by the water molecules. Therefore, the present study shows that the polysiloxane-grafted insulation paper cellulose can improve its thermal stability in micro-water environment.

Abstract licence: CC BY

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