Photocatalytic cyclization of nitrogen-centered radicals with carbon nitride through promoting substrate/catalyst interaction
Mingcheng Yang, Ronghong Lian, Xirui Zhang and 3 more
Nature Communications · 2022
doi:10.1038/s41467-022-32623-3 (opens in a new tab)
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Abstract
Carbon nitride catalysts with positively charged surfaces and abundant −NH2 are found to be effective photocatalysts for dihydropyrazole synthesis. A surface-mediated mechanism where deprotonated intermediates interact with the surface is proposed.
Abstract licence: CC BY-NC-ND
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