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Relief of excited-state antiaromaticity enables the smallest red emitter

Heechan Kim, Woojin Park, Younghun Kim and 3 more

Nature Communications · 2021

doi:10.1038/s41467-021-25677-2 (opens in a new tab)

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Abstract

Commonly, large π-conjugated systems facilitate low-energy electronic transitions. Here, the authors demonstrate that the relief of excited-state antiaromaticity of the benzene core leads to large Stokes shifts, and allows the construction of emitters covering the entire visible spectrum without the need of extending π-conjugation.

Abstract licence: CC BY-NC-ND

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