Rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C−H activation
Dingyi Wang, Ben Dong, Yandong Wang and 4 more
Nature Communications · 2019
doi:10.1038/s41467-019-11420-5 (opens in a new tab)
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Abstract
Dialkyl biaryl phosphines find wide application in catalysis as ligands. Here, the authors report a rhodium-catalysed hydroarylation of alkenes and alkynes with tertiary phosphines through P(III)-chelation assisted C-H activation affording a library of functionalized phosphines which hold potential in catalytic applications.
Abstract licence: CC BY-NC-ND
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