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Short-channel field-effect transistors with 9-atom and 13-atom wide graphene nanoribbons

Juan Pablo Llinas, Andrew Fairbrother, Gabriela Borin Barin and 21 more

Nature Communications · 2017 · CC BY

doi:10.1038/s41467-017-00734-x

Abstract

Bottom-up synthesized graphene nanoribbons and graphene nanoribbon heterostructures have promising electronic properties for high-performance field-effect transistors and ultra-low power devices such as tunneling field-effect transistors. However, the short length and wide band gap of these graphene nanoribbons have prevented the fabrication of devices with the desired performance and switching behavior. Here, by fabricating short channel ( L ch ~ 20 nm) devices with a thin, high- κ gate dielectric and a 9-atom wide (0.95 nm) armchair graphene nanoribbon as the channel material, we demonstrate field-effect transistors with high on-current ( I on > 1 μA at V d = −1 V) and high I on /I off ~ 10 5 at room temperature. We find that the performance of these devices is limited by tunneling through the Schottky barrier at the contacts and we observe an increase in the transparency of the barrier by increasing the gate field near the contacts. Our results thus demonstrate successful fabrication of high-performance short-channel field-effect transistors with bottom-up synthesized armchair graphene nanoribbons.

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References 36

  1. 1.

    Cai J, et al. Atomically precise bottom-up fabrication of graphene nanoribbons. Nature. 2010;466:470-473.

    Not in our library10.1038/nature09211

  2. 2.

    Chen Y-C, et al. Tuning the band gap of graphene nanoribbons synthesized from molecular precursors. ACS Nano. 2013;7:6123-6128.

    Not in our library10.1021/nn401948e

  3. 3.

    Narita A, et al. Synthesis of structurally well-defined and liquid-phase-processable graphene nanoribbons. Nat. Chem. 2014;6:126-132.

    Not in our library10.1038/nchem.1819

  4. 4.

    Narita A, Wang X-Y, Feng X, Müllen K. New advances in nanographene chemistry. Chem. Soc. Rev. 2015;44:6616-6643.

    Not in our library10.1039/c5cs00183h

  5. 5.

    Ruffieux P, et al. On-surface synthesis of graphene nanoribbons with zigzag edge topology. Nature. 2016;531:489-492.

    Not in our library10.1038/nature17151

  6. 6.
  7. 7.

    Talirz L, et al. On-surface synthesis and characterization of 9-atom wide armchair graphene nanoribbons. ACS Nano. 2017;11:1380-1388.

    Not in our library10.1021/acsnano.6b06405

  8. 8.

    Talirz L, Ruffieux P, Fasel R. On-surface synthesis of atomically precise graphene nanoribbons. Adv. Mater. 2016;28:6222-6231.

    Not in our library10.1002/adma.201505738

  9. 9.

    Chen Y-C, et al. Molecular bandgap engineering of bottom-up synthesized graphene nanoribbon heterojunctions. Nat. Nanotechnol. 2015;10:156-160.

    Not in our library10.1038/nnano.2014.307

  10. 10.

    Cai J, et al. Graphene nanoribbon heterojunctions. Nat. Nanotechnol. 2014;9:896-900.

    Not in our library10.1038/nnano.2014.184

  11. 11.

    Nakada K, Fujita M, Dresselhaus G, Dresselhaus MS. Edge state in graphene ribbons: nanometer size effect and edge shape dependence. Phys. Rev. B. 1996;54:17954-17961.

    Not in our library10.1103/physrevb.54.17954

  12. 12.

    Yang L, Park C-H, Son Y-W, Cohen ML, Louie SG. Quasiparticle energies and band gaps in graphene nanoribbons. Phys. Rev. Lett. 2007;99:186801.

    Not in our library10.1103/physrevlett.99.186801

  13. 13.

    Hsu H, Reichl LE. Selection rule for the optical absorption of graphene nanoribbons. Phys. Rev. B. 2007;76:45418.

    Not in our library10.1103/physrevb.76.045418

  14. 14.

    Yoon Y, Guo J. Effect of edge roughness in graphene nanoribbon transistors. Appl. Phys. Lett. 2007;91:73103.

    Not in our library10.1063/1.2769764

  15. 15.

    Franklin AD. Electronics: the road to carbon nanotube transistors. Nature. 2013;498:443-444.

    Not in our library10.1038/498443a

  16. 16.

    Bennett PB, et al. Bottom-up graphene nanoribbon field-effect transistors. Appl. Phys. Lett. 2013;103:253114.

    Not in our library10.1063/1.4855116

  17. 17.

    Abbas AN, et al. Deposition, characterization, and thin-film-based chemical sensing of ultra-long chemically synthesized graphene nanoribbons. J. Am. Chem. Soc. 2014;136:7555-7558.

    Not in our library10.1021/ja502764d

  18. 18.

    Abbas AN, et al. Vapor-phase transport deposition, characterization, and applications of large nanographenes. J. Am. Chem. Soc. 2015;137:4453-4459.

    Not in our library10.1021/ja513207e

  19. 19.

    Gao J, et al. Ambipolar transport in solution-synthesized graphene nanoribbons. ACS Nano. 2016;10:4847-4856.

    Not in our library10.1021/acsnano.6b00643

  20. 20.

    Verzhbitskiy IA, et al. Raman fingerprints of atomically precise graphene nanoribbons. Nano Lett. 2016;16:3442-3447.

    Not in our library10.1021/acs.nanolett.5b04183

  21. 21.

    Vandescuren M, Hermet P, Meunier V, Henrard L, Lambin P. Theoretical study of the vibrational edge modes in graphene nanoribbons. Phys. Rev. B. 2008;78:195401.

    Not in our library10.1103/physrevb.78.195401

  22. 22.

    Hazeghi A, Krishnamohan T, Wong HSP. Schottky-barrier carbon nanotube field-effect transistor modeling. IEEE Trans. Electron Devices. 2007;54:439-445.

    Not in our library10.1109/ted.2006.890384

  23. 23.

    Appenzeller J, Radosavljević M, Knoch J, Avouris P. Tunneling versus thermionic emission in one-dimensional semiconductors. Phys. Rev. Lett. 2004;92:48301.

    Not in our library10.1103/physrevlett.92.048301

  24. 24.

    Appenzeller J, et al. Field-modulated carrier transport in carbon nanotube transistors. Phys. Rev. Lett. 2002;89:126801.

    Not in our library10.1103/physrevlett.89.126801

  25. 25.

    Chen Z, Appenzeller J, Knoch J, Lin Y, Avouris P. The role of metal−nanotube contact in the performance of carbon nanotube field-effect transistors. Nano Lett. 2005;5:1497-1502.

    Not in our library10.1021/nl0508624

  26. 26.

    Perebeinos V, Tersoff J, Haensch W. Schottky-to-Ohmic crossover in carbon nanotube transistor contacts. Phys. Rev. Lett. 2013;111:236802.

    Not in our library10.1103/physrevlett.111.236802

  27. 27.

    Zhang Y, Ye J, Matsuhashi Y, Iwasa Y. Ambipolar MoS2 thin flake transistors. Nano Lett. 2012;12:1136-1140.

    Not in our library10.1021/nl2021575

  28. 28.

    Franklin AD, et al. Sub-10 nm carbon nanotube transistor. Nano Lett. 2012;12:758-762.

    Not in our library10.1021/nl203701g

  29. 29.

    Jiao L, Zhang L, Wang X, Diankov G, Dai H. Narrow graphene nanoribbons from carbon nanotubes. Nature. 2009;458:877-880.

    Not in our library10.1038/nature07919

  30. 30.

    Li X, Wang X, Zhang L, Lee S, Dai H. Chemically derived, ultrasmooth graphene nanoribbon semiconductors. Science. 2008;319:1229-1232.

    Not in our library10.1126/science.1150878

  31. 31.

    Wang X, Dai H. Etching and narrowing of graphene from the edges. Nat. Chem. 2010;2:661-665.

    Not in our library10.1038/nchem.719

  32. 32.

    Jacobberger RM, et al. Direct oriented growth of armchair graphene nanoribbons on germanium. Nat. Commun. 2015;6:8006.

    Not in our library10.1038/ncomms9006

  33. 33.

    Luisier, M., Lundstrom, M., Antoniadis, D. A. & Bokor, J. Ultimate device scaling: intrinsic performance comparisons of carbon-based, InGaAs, and Si field-effect transistors for 5 nm gate length. 2011 International Electron Devices Meeting, Washington, DC, 2011, pp. 11.2.1-11.2.4.

    Not in our library

  34. 34.

    Linden S, et al. Electronic structure of spatially aligned graphene nanoribbons on Au(788). Phys. Rev. Lett. 2012;108:216801.

    Not in our library10.1103/physrevlett.108.216801

  35. 35.

    Zhao P, Chauhan J, Guo J. Computational study of tunneling transistor based on graphene nanoribbon. Nano Lett. 2009;9:684-688.

    Not in our library10.1021/nl803176x

  36. 36.

    Franklin AD, Chen Z. Length scaling of carbon nanotube transistors. Nat. Nanotechnol. 2010;5:858-862.

    Not in our library10.1038/nnano.2010.220

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